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"notes":{"slide-46":"Y así quedo toda la zona seis meses después, con los lodos retirados.",
"slide-50":"Y todo esto en unas condiciones muy duras, con todo tipo de protecciones y a 40º, lo que hacía el trabajo muy engorroso, ... claro que nosotros pertenecíamos a otra empresa.",
"slide-102":"La alteración se pone claramente de manifiesto al estudiar estas muestras.\nEn el fondo del perfil, a unos 70/80cm, los suelos carbonatados muestran tanto a nivel macro, en campo, como en laboratorio, al microscopio óptico, un aspecto similar al del los suelos no contaminados.\nPor encima la capa acre-rojiza muestra una importante alteración. El Fe de la solución contaminante precipita formando compuestos de color ocre-rojizo gene. mal cristalizados que agregan a los granos mine. que han resistido, en > o < grado, la alteración de la solución ácida y aparecen abundantes cristales de yeso.\nEn la capa más superficial, la gris-blanca la alteración es máxima. La infiltración de la sol ácida procedente de los lodos, con un pH tan bajo como 1,8 destruye totalmente a la mayoría de los minerales y aparece un residuo formando unas masas de baja cristalinidad. Como resultado de la hidrólisis mineral aparecen espacios vacíos en el suelo (en negro en la imagen) que se agrupan también horizontalmente. La estructura del suelo se destruye y adopta un tipo laminar.\nEn el SEM se observa el aspecto vítreo de este residuo y el micro análisis por energías dispersivas de rayos X muestra una composición de Fe y S aportados por la sol ácida contaminante procedente de los lodos, junto a Si, Al, Mg, Ca y K procedentes de la alteración mineral.",
"slide-51":"Pero la situación realmente no estaba para muchas bromas, pues había también una contaminación eólica muy fuerte.",
"slide-47":"Realmente se realizó una labor faraónica y en un tiempo record.\nSe movieron más de 7 millones de metros cúbicos de lodos y suelos. Como se había calculado que el vertido correspondiente a los lodos fue del orden de 1 millon de m3 pues se perdieron en la zona unos 6 millones de m3 de suelos, lo representa que los suelos se decapitaron una media de más de 30 cm, los 30 cm superficiales, donde radica fundamentalmente la fertilidad del suelo.  Por otra parte, se calcula que los camiones que transportaron los lodos pudieron dar 350 vueltas a la Tierra por el ecuador.\ndumper grande 25 m3 = 280.000 portes;   una hilera de 1.960 km;\ncada porte una media de 50km de ida y vuelta;  280000 x 50 = 14.000.000 km; \ncircunferencia de la tierra 40.000 km;  350 vueltas a la tierra\n\n4.400 hectáreas = 4.400 *10.000 = 44 millones de m2.\n7 millones de m3 / 44 = 16 cm de espesor de suelo",
"slide-52":"Bueno, con la retirada de los lodos la contaminación se redujo sensiblemente.",
"slide-103":"Los carbonatos son los primeros que desaparecen. En el nivel más superficial de la capa ocre-rojiza, ya a los dos meses bajan de un 15% que tenía el suelo original a un 5%, para desaparecer por completo a los 15 meses.\nConforme va pasando el tiempo el paquete de suelo completamente decarbonatado va aumentando de espesor, la descarbonatación parcial alcanza hasta los 80 cm de profundidad a los 9 años.",
"slide-49":"Los lodos con la capa superficial de los suelos se llevaron a la antigua corta, que se relleno en gran medida.",
"slide-53":"Se había conseguido rebajar la contaminación en algo más de un 30%  (siempre trabajando sobre fracción total, valores medios y en muestras de horizontes superficiales), pero los resultados no eran demasiado gratificantes. ",
"slide-54":"Pues después de retirar siete millones de metros cúbicos de lodos y suelos y gastar más de 100 millones de euros,la contaminación era mayor de la que hubo en un primer momento.  ¡Sólo se había rebajado la contaminación secundaria en aproximadamente un 30%.¡Había que seguir trabajando!",
"slide-104":"Tras los carbonatos se alteran también los feldespatos y los filosilicatos, mientras que el cuarzo resiste aparentemente.",
"slide-2":"Esta charla la vamos a estructurar en cinco apartados. Empezaremos recordando como fue el accidente minero.",
"slide-55":"En los años siguientes, durante el 1999 y 2000 se llevaron a cabo una serie de medidas enmendantes.",
"slide-4":"En el tercer bloque hablaremos de las medidas de remediación que se llevaron a cabo. ",
"slide-56":"Que la zona no había quedado totalmente limpia, lo pudimos comprobar directamente en el campo. En julio así estaba esta zona y",
"slide-60":"y así se hizo, pero las parcelas de experimentación fracasaron; algunas no germinaron, el muchos casos desarrollo de las plantas fue escaso, otras se secaron y la absorción final de metales en la parcela fue muy escasa. Por todo ello la experiencia se abandonó.\nVicario: Brassica juncea (recolección 3000 kg/ha y año)\nAs cantidad a extraer 600 kg/ha. extracción 0,6 g/ha año . Número de cosechas 1.000.000\nPb                              370                             1,6                                                           230.000    \nCu                              149                             3,1                                                            48.000\nZn                            1224                           80,5                                                            15.000",
"slide-105":"Por otra parte, los iones disueltos en la solución contaminante junto a los procedentes de la alteración mineral precipitan formando nuevos compuestos. Dada la abundancia de S y de Fe en la solución contaminante, los minerales neoformados son hidroxisulfatos  y oxihidróxidos fundamentalmente de Fe, pero también de otros cationes como el Ca y K liberados por los minerales primitivos.\nAsí el mineral neoformado más abundante es el yeso, como muestran el diagrama de energías dispersivas, y se distribuye por todo el perfil contaminado presentando sus típicos hábitos tabulares, en maclas y formando rosetas, visibles a simple vista. ",
"slide-61":"Bien se había hecho lo que se podía para eliminar contaminantes. ¿Qué otra cosa se podía hacer?\nPues se pensó que si no se podía eliminar más contaminantes se buscó en, al menos, inmovilizarlos.",
"slide-57":"tan sólo dos meses después ofrecía este aspecto. Con las escasas lluvias del verano el aspecto de la zona había cambiado.",
"slide-6":"Y terminaremos aventurándonos en el previsible futuro de esta región.",
"slide-62":"Para ello lo primero que se hizo fue determinar como de móviles se encontraban y a que constituyentes del suelo mostraban más afinidad, para lo cual se realizó una serie de extracciones a las muestras de suelos con diversos agentes: agua para los solubles, cloruro cálcico para los metales adsorbidos en el complejo de cambio, ácido acético para conocer los contaminantes ocluídos con los carbonatos, oxalato-oxálico para los fijados por los compuestos de Fe, y para englobar a todos los que se presentaban en fase asimilable por las plantas se utilizó el EDTA. En general las extracciones fueron altas ...\nEDTA = Acido etilendiaminotetraacético",
"slide-8":"Pertenece a la Faja Pirítica Ibérica que recorre en dirección este-oeste el sur del la Península Ibérica y se encuentra situada justo en el límite entre el macizo de Sierra Morena y la Depresión del Guadalquivir.\nEn la imagen se observa en azul intenso la balsa de almacenamiento de estériles que fue la causante del vertido, de unos 2 km de longitud, situada junto al río Agrío, que es afluente del río Guadiamar.\npyrite (83.1%), sphalerite (5.4%), galene (2.1%), chalcopyrite (1.4%) and arsenopyrite (0.9%), as well as minor amounts of bournonite, boulangerite, nuffieldite, jaskolskiite",
"slide-106":"A lo largo del perfil se establece un gradiente en el pH y en los contenidos en Fe y S que van a condicionar el tipo de minerales neoformados.\nEn la capa blanca y en la parte superficial de la capa rojiza, aparece un hidroxisulfato de Fe con K, que identificamos como jarosita, formando agregados de pequeños cristales con formas pseudocúbicas, en esta otra imagen recubriendo a un prisma de yeso. \nSe forma en los niveles más fuertemente ácidos y con abundancia de S, con razones molares Fe/S de entre 1,3 y 1,5.",
"slide-110":"En definitiva la composición mineral cambia totalmente, desaparecen los minerales del suelo original que van siendo sustituidos por minerales neoformados. ",
"slide-58":"Lo primero que se hizo fue relimpiar las zonas que habían quedado más contaminadas a costa de perder gran cantidad de suelo y se consiguió rebajar bastante la contaminación aunque no lo suficiente (la concentración media seguía por encima del NI).",
"slide-59":"Para seguir eliminado contaminantes se pensó en la fitorremediación.\nSe pensó, en un primer momento, importar plantas de Africa de probado poder de asimilación de As y metales, pero se desechó por la dificultad de su aclimatación y se optó por plantar plantas autóctonas",
"slide-63":"Y estos fueron los agentes bloqueantes añadidos\nPara los carbonatos: se hicieron pruebas en el laboratorio del poder encalante con carbonato de calcio puro, cenizas de celulosa, lodo de depuradora y espumas de azucarera.\nSe eligieron las espumas de azucarera por: High CaCO3 content (40%), Very fine particle size (reactive), High OM content (15-20%), Cheap (industrial waste).\nPara calcular la cantidad de a añadir de espumas de azucarera se hizo una valoración en el laboratorio del poder neutralizante de la acidez.\nFinalmente se añadieron 4 kg m-2 (es decir, 40.000 kg/ha) en la zona ácida (max. 15) y 2 kg m-2 zona neutra y básica. \nPara los óxidos de Fe y las arcillas (bentonitas) se hicieron pruebas en parcelas experimentales y se añadió un suelo rico en óxidos de Fe y arcillas a 20.000 kg/ha.\nCon la materia orgánica hubo problemas en su adquisición y sólo se añadió a una pequeña parte de la zona.\n",
"slide-111":"La alteración se pone también claramente de manifiesto en el pH del suelo. \nLos suelos básicos, con carbonatos, (representados en azul y verde) experimentan una intensa acidificación en sus horizontes superficiales. Mientras que en los suelos sin carbonatos (en rojo y naranja) la extrema acidez llega hasta casi los 3 metros (la máxima profundidad de muestreo que hemos alcanzado, en un suelo a los 9 años).",
"slide-64":"Además con los carbonatos se podía neutralizar la acidez y conseguir la inmovilización de muchos metales que eran mucho más móviles (de hasta casi 50 veces) en los suelos ácidos frente a los básicos, como se observa en estas gráficas en las que se compara el porcentaje del elemento traza soluble frente al total en los suelos ácidos y básicos. Por ejemplo, soluble el 28 y 22% para Zn y Cd en los ácidos que baja o menos del 1% en los básicos.",
"slide-107":"Los hidroxisulfatos de Fe se presentan en toda la capa rojiza, pero hemos tenido muchas dificultades para poderlos identificar. \nEn la parte media de la capa rojiza encontramos un hidroxisulfatos de Fe con importante contenido en S, aunque claramente menos S que la jarosita, por su ratio molar Fe/S de 1,9 a 2,3  y el pH de 4,3 a 5,4 y por la forma observada en el SEM pensamos en la fibroferrita",
"slide-65":"Bien, aparte de eliminar e inmovilizar los contaminantes ¿Que más se podía hacer?. Pues se pensó en que si no se podían extraer ni bloquear más contaminantes, al menos se podría intentar diluirlos. ",
"slide-108":"Similar a la situación anterior, algo más profundo, aparecen otros hidroxisulfatos de Fe, ya con menos S que la fibroferrita, y noas condiciones de pH no tan extremas, que podría corresponder a una variedad del tipo de la schwertmanita.",
"slide-70":"Y con las lluvias los metales eran arrastrados por las aguas de escorrentía.",
"slide-112":"En cuanto a la contaminación en estos suelos que han conservado la capa superficial de lodos, podemos ver como es extrema, con un comportamiento muy distinto en los suelos ácidos frente a los básicos.\nEn los suelos sin CO3 (con líneas roja y naranja) claramente es más intensa y profunda que los que si contienen CO3 (líneas verde y azul). La conta en los suelos con CO3 se concentra en los primeros cm del suelo en los que es muy intensa (en los primeros mm para el As y el Pb), en los hor de pH ácido; y como rasgo importante tenemos que la conta no sobrepasa los 60 cm de prof en las muestras de 9 años, queda pues la contaminación bloqueada en el suelo, no llega al subsuelo ni a los niveles freáticos. \nPor el contrario, en los suelos sin CO3 el As y los metales pesados llegan a alcanzar grandes profundidades y salir del suelo hacia el subsuelo y contaminar a las aguas freáticas. \nEn cuanto al grado de movilidad, el Cu parece ser el más móvil, seguido del Zn, Pb y As que parece ser el menos móvil.",
"slide-66":"Como en el horizonte superficial era donde se producían las máximas concentraciones se podría mezclar este con el horizonte subsuperficial que estaba menos contaminado. Eran los mismos contaminantes pero mejor repartidos.",
"slide-67":"un simple arado profundo en toda la zona podría servir.",
"slide-71":"La últimas medidas buscaron un freno a la escorrentía y a la erosión, en definitiva había que estabilizar la nueva superficie del terreno.",
"slide-109":"En el límite inferior de la capa rojiza apenas si se acumula azufre y se forman oxihidróxidos de Fe, del tipo de la ferrihidrita, goethita y hematites ",
"slide-113":"En definitiva la extrema contaminación en estos suelos con lodos hace que no haya desarrollo vegetal.",
"slide-72":"para ello se procedió a una intensa campaña de revegetación",
"slide-68":"El arado fue esencial en la zona ácida en la que los suelos había sufrido un fuerte encostramiento superficial, impidiendo por completo el desarrollo de las plantas.",
"slide-73":"se sembraron gramíneas y otras especies autóctonas. Y numerosas especies arbóreas ...",
"slide-69":"Pero a los pocos meses del arado del suelo todavía la zona mostraba claros signos de degradación. La superficie no estaba estabilizada. Había intensos signos de fuertes escorrentías y erosión.",
"slide-114":"Nosotros para para probar la toxicidad de estos suelos en los que ha permanecido el lodo en superficie hemos llevado a cabo pruebas de toxicidad realizadas con una bacteria (VF), dos especies vegetales (L y M) y con lombrices de tierra. Un resumen de los resultados lo esquematizamos en esta imagen. En ella se observa como en la capa blanca hay una ausencia total de actividad biótica y un desarrollo biológico muy limitado en la capa roja.\nAbajo, fuera de la capa roja, el suelo muestra una actividad normal.",
"slide-74":"en muchísimos casos los arboles plantados fracasaron,",
"slide-75":" pero en otros muchos casos si se desarrollaron ... como es el caso de los ...\n(pino piñonero)",
"slide-115":"Y para terminar, vamos a permitirnos una mirada al futuro.\n¿Qué futuro podemos esperar para la zona?",
"slide-10":"5 millones de m3 es una cifra impresionante, pero difícil de imaginar, podemos hacernos una idea si la comparamos al volumen de la Puerta del Sol de Madrid.",
"slide-80":"y ya las concentraciones de todos los contaminantes eran más bajas que las que se produjeron en el primer momento del vertido, se había rebajado del orden del 20 al 50%,\n\nCon estos aceptables resultados, ya no llevó a cabo ninguna labor de remediación importante. La Junta de Andalucía  y los políticos perdieron el interés por el vertido.",
"slide-76":"Para evitar que cualquier posible actividad agrícola en estos suelos pudiera repercutir desfavorablemente en la aceptación por los mercados de los productos agrícolas de la región, la zona del vertido se expropió, se cercó, se estableció lo que se llama el Corredor Verde del Guadiamar, corredor entre las marismas y Sierra Morena y se prohibió cualquier uso, no sólo agrícola sino",
"slide-11":"en este caso el volumen del vertido equivaldría a una 23 veces el volumen de la Puerta del Sol de Madrid.",
"slide-81":"pero todavía las concentraciones eran mas altas que las que presentaban los suelos antes del vertido (con incrementos muy importantes para el As del 438%)",
"slide-116":"Empecemos considerando como hubiese evolucionado la zona si no se hubiese remediado.\nA la hora de considerar la posible fertilidad del suelo un factor decisivo lo constituye el pH del suelo.\nComo hemos visto la capa superficial sufre una intensa acidificación. Podemos aceptar que por debajo de un pH de 3,5 no habrá actividad biológica. Este pH se alcanza a los 3 años en los 3 cm superficiales, se profundiza hasta los 6 cm a los 4 años, después la capa con pH ≤ 3,5 alcanza los 8 cm a los 6 años y termina a los 9 años afectando a los 10 primeros cm.\n",
"slide-77":"también se prohibió la pesca y el pastoreo ...",
"slide-120":"34 cm a los 30 años",
"slide-12":"Esta contaminación se vierte sobre el cauce y ribera de los ríos Agrio y Guadiamar afectando a una superficie de unas  4.400 ha, principalmente de terrenos agrícolas. \nSiguiendo nuestro símil la Puerta del Sol tiene un área de casi una hectárea.",
"slide-82":"A partir del 2001 ya no se llevó a cabo ninguna labor de remediación importante, pero en nuestro seguimiento de los años 2004, 2009 y 2010 las concentraciones han seguido disminuyendo del orden de un 10 a un 20% con respecto a las últimas medidas de remediación y",
"slide-78":"aunque luego cada aquí, en este país nuestro, cada uno interpreta las normas a su manera.",
"slide-13":"El vertido se distribuye por el cauce y la ribera del río Agrío primero y luego del Guadiamar, alcanzando las aguas unos 50 km y los lodos 40. Con una anchura media de unos 400 metros, pero muy variable, dependiendo de la microtopografía.",
"slide-117":"Si establecemos una ecuación de regresión entre el espesor de la capa de pH ≤ 3,5 y el tiempo, vemos que sigue una tendencia lineal, con un alto coeficiente de correlación.",
"slide-83":"disminuyendo también si comparamos a la contaminación inicial, pero",
"slide-79":"Las medidas de remediación terminaron prácticamente en el año 2000. Al año siguiente las muestras analizadas de los suelos mostraban claros decrecimientos",
"slide-121":"y así sucesivamente",
"slide-14":"En cuanto a la composición del vertido, las aguas llevaban importantes cantidades de metales disueltos, fundamentalmente Zn, con 73 mg/L. \nA destacar la concentración de un metal tan tóxico como es el Cd que se encontraba en una concentración que rebasaba en casi 70 veces los límites permitidos para el agua de riego. También importante la ausencia en las aguas de dos elementos tan peligrosos como el As y el Hg.\nImportante también señalar el pH, fuertemente ácido, alrededor de 3,5.",
"slide-84":"pero desgraciadamente todavía las concentraciones medias de los suelos, en su horizonte superficial, se encuentran por encima de los valores de los suelos de antes del vertido, hasta mas de un 300% para el As.\n",
"slide-15":"Las concentraciones de los lodos, como es lógico, eran mucho más altas. Especialmente para el Pb, Zn (del orden de 9 mil y 8 mil mg/kg), concentraciones también muy importantes para As y Cu (4 mil y 2 mil) (el As, superaba en 54 veces el nivel máximo permitido para la utilización de un lodo para fines agrícolas); y menores concentraciones para Sb, Ba, y menores aún para otros metales como Bi, Cr, Tl, Co, V, Cd y Ni.",
"slide-85":"No obstante el valor medio de todos los contaminantes estaban por debajo de los niveles de intervención establecidos para parques.\nPero ¡ojo!, estamos hablando de valores medios, esto sólo representa el valor medio para los suelos. De hecho hasta este momento sólo hemos hablado de valores medios, pero es muy importante conocer el comportamiento de la toda la población de suelos, para conocer, por ejemplo cuantos suelos presentan concentraciones superiores al valor establecido para el nivel de intervención. Para ello podemos recurrir a los percentiles.",
"slide-118":"Si extrapolamos esta tendencia podríamos tener una representación similar a esta secuencia. La capa hiperácida con 14 cm en la situación actual.",
"slide-20":"Veamos el comportamiento de un suelo representativo de cada zona.\nEn los suelos arenosos, de la parte alta de la cuenca, con muy bajo grado de desarrollo de la estructura, los lodos apenas penetraron en los suelos y quedaron en gran medida depositados sobre la superficie.\u2028En los suelos de la cuenca media, moderadamente arcillosos y con un moderado grado de desarrollo estructural, la penetración de los lodos ...\nEn los suelos arcillosos, con un fuerte desarrollo de la estructura (especialmente los de la parte baja de la cuenca), los lodos penetraron con facilidad a través de las grietas estructurales y gran parte de ellos quedaron retenidos dentro del suelo hasta los 50 cm de profundidad.\nEn definitiva la entrada de lodos fue muy desigual (desde sólo unos gramos de lodo por kg en los suelos mas arenosos hasta más de 150 g/kg en los más arcillosos) en el horizonte superficial.",
"slide-90":"Si comparamos la situación actual con la que se presentaba en el año del vertido vemos que la situación ha mejorado sensiblemente. En aquel año superaban los N.I. el 7% de los suelos para el Cd, el 8% para Cu, 11% para Tl, y 26% para el Pb mientras que en 2009 no se supera en ningún caso para ninguno de estos metales. El Zn ha pasado de superarse el 42% en 1998 a sólo el 5% en las muestras actuales. Pero queda el problema del As, que aunque se ha mejorado bastante, del 68% hemos pasado al 24% de suelos potencialmente tóxicos.\nSi bien hemos de aclarar que esta tablas tienen una pequeña argucia. Y es los valores de los niveles de intervención que se usa en cada situación. Efectivamente los N.I. de 1988 está referidos a suelos agrícolas mientras que para el 2009 hemos usado los N.I. para suelos de parques, y como sabemos con valores de los límites más altos, pero es que estos son los usos reales de los suelos en cada fecha, por tanto el criterio utilizado lo consideramos totalmente correcto.\nPodemos pues afirmar rotundamente que las medidas de remediación llevadas a cabo deben ser valoradas muy positivamente, aunque en honor a la verdad a quedado con cierta contaminación.",
"slide-86":"En estas gráficas podemos ver como la tendencia general es a bajar las concentraciones de los percentiles al ir transcurriendo el tiempo.",
"slide-16":"Bien, esas aguas y esos lodos cayeron sobre los suelos y los contaminaron. Este es el aspecto que presentaba la zona a los 10 días del vertido, los suelos se encontr recubiert de una capa de lodos como si tuviesen una coraza metálica de unos 8 cm de esp que los fosilizaba.\nPara evaluar el impacto se muestrearon los suelos en distintas fechas.\nEn un principio se selec 7 puntos represen, a los 10, 25 y 40 días del vertido, después pasamos a establecer una red de muestreo con 100 puntos repartidos aleatoriamente por la toda la zona contaminada, al final del año 1998, en 1999, 2001, 2004, 2009 y 2010. A tres prof ... lógica el hor sup 0-10 fue donde se presentaron las mayores conc y es por ello al que nos vamos a referir en esta charla.\n",
"slide-119":"que pasaría a ser de 23 cm a los 20 años del vertido",
"slide-17":"El impacto sobre los suelos va a depender en gran medida de las características de estos, ya que según sean estas los suelos van a poseer un poder de autodepuración muy variable. \nFrente a este vertido ácido los suelos de la cuenca presentaban muy buenas características en lo referente al pH (siempre neutro o básico, nunca ácido) y al contenido en carbonatos para gran número de ellos; y moderadas prestaciones para los contenidos en materia orgánica, capacidad de cambio de cationes y para el Fe.\nSe trataba de los suelos típicos de la riberas de los ríos, suelos muy poco evolucionados en todos los casos.",
"slide-1":"Bien el vertido pirítico de Aznalcóllar constituye un caso insólito en España; un caso insólito por varios motivos: \n1º por la extensión de la contaminación (fueron varios miles las ha afectadas directamente)\n2º por su situación (cercanías al Parque Nacional de Doñana; se afectó el Parque Natural y quedó a las puertas del Parque Nacional), y \n3º por la sensibilidad que tuvo la sociedad que arrastró a los políticos y hubo una reacción inmediata de la comu científ para analizar la graved del probl.\nHan sido muchos los equipos que han trabajado en las consecuencias de este vertido bajo muy diversos aspectos, como la hidrología, la botánica, la zoología,.... Concretamente en los suelos han trabajado varios grupos, por ejemplo a destacar la labor realizada por un equipo gallego dirigido por los doctores Macías y Calvo, también han realizado importantes contribuciones investigadores varias universidades, sin olvidar a los investigadores del CSIC. Resumir todo ello se sale de los límites de esta charla. Yo les voy a exponer hoy algunos de los resultados obtenidos por el Dpto Eda Univ Gr, en el seguimiento realizado sobre los suelos desde los primeros días del vertido hasta la actualidad y de la medidas remediadoras que adoptó la Junta de Andalucía en base a los resultados que iban obteniendo de todos estos equipos. Intentaré mostrarles como está la situación hoy.\nPero esta investigación tiene un interesante valor añadido y es comprobar como un departamento universitario afronta una situación nueva, para la que no está especialmente preparado. Efectivamente nosotros éramos especialistas en varias líneas sobre suelos, como la génesis, mineralogía, micromorfología, cartografía y evaluación pero no habíamos investigado nada sobre la contaminación por metales pesados. Fuimos a Aznalcóllar simplemente por curiosidad, para tomar unas fotos y unas muestras para mostrárselas a nuestros alumnos. Pero lo que allí nos encontramos fue de tal magnitud que nos obligó a dedicarle toda nuestra atención. En definitiva se puede decir que el vertido tóxico de Aznalcóllar supuso un cambio radical en las líneas de investigación de nuestro departamento.  ",
"slide-91":"Bien queda contaminación pero de cualquier forma la situación no es tan grave como la veían algunos",
"slide-87":"Si referimos estas concentraciones a las de los niveles de intervención de los suelos de parques naturales, destacamos como para el Cd, Tl, Cu y Pb a partir del 2004  el 100% de los suelos está por debajo de este N.I.; En cuanto al Zn en el 2010 tenemos el 95 percentil con concentraciones por debajo del N.I., es decir sólo un 5% de los suelos podría considerase como potencialmente contaminado; y sólo para el As encontramos una situación delicada.",
"slide-21":"Por otra parte, los suelos actuaron también como un sistema depurador que retuvieron gran parte del As y de los metales pesados disueltos en las aguas. El poder de autodepuración fue muy desigual, dependiendo fundamentalmente de las propiedades fisicoquímicas de cada suelo, pero condicionadas por las propiedades físicas.",
"slide-22":"En esta figura representamos la contaminación aportada por las aguas para uno de los metales pesados, el Cd, en estos tres suelos representativos, con diferentes texturas.\nEl efecto depurador fue muy bajo en los arenosos, moderado en los francos y muy alto en los arcillosos.\n",
"slide-88":"Si vemos la gráfica del As ampliada podemos observar que en el 2010 el percentil 76 tiene una concentración por debajo del N.I., o sea que un 24% de los suelos en las muestras actuales de 2010 superan este N.I de 100 mg/kg",
"slide-18":"En líneas generales, en la distribución de estos suelos se pueden diferenciar en tres zonas:\n- en la parte alta de la cuenca, junto a la mina, predominan los suelos sin carbonatos y de textura arenosa, por tanto son los suelos más sensibles a la contaminación, es pues la zona más frágil,\n- en la zona media, están ya presentes los carbonatos, pero siguen presentando una textura desfavorable,\n- finalmente, en la parte baja de la cuenca, se encuentran los suelos con mayor poder de autodepuración: con carbonatos y con arcillas y limos.\nFrente a la contaminación, los suelos actuaron protegiendo al medio ambiente bajo dos procesos distintos.",
"slide-3":"Después pasaremos a considerar el impacto en los suelos",
"slide-92":"Pero tampoco la situación era tan optimista como la veían otros como ...\nComo hemos mostrado en anteriores imágenes, la situación real es que si bien sólo hay posibles problemas de toxicidad para el As en un 24% de los suelos, el resto de metales pesados aunque no se han superado los límites de peligrosidad si han quedado los suelos con unos incrementos que oscilan entre el 30 y el 300% con respecto a los concentraciones antes del vertido. ¡Decir que la zona ha quedado más limpia ... con un incremento de casi el 300% de As!\nBien parece probado que en la zona ha quedado un problema importante con el As, que supera el NI en un 24% de los suelos. Pero todavía podemos precisar más. Ahora debemos plantearnos como de peligroso es este As, es decir como se encuentra este As. ¿Está soluble y por tanto es tóxico o está en gran parte insoluble y por tanto sólo es potencialmente tóxico para un posible futuro?.",
"slide-23":"De esta contaminación una pequeña parte, la representada en azul oscuro, es la debida al agua que quedó retenida en los poros, pero un aspecto muy importante lo representa la contaminación (que en realidad podemos hablar de depuración) de la parte del agua representada en color celeste, esta la atribuimos al agua de gravedad que al infiltrarse la solución contaminante en el suelo ha ido purificándose, depositando (por adsorción y precipitación) los elementos contaminantes y dejando percolar el agua mucho más limpia hacia los niveles freáticos.\nEl efecto depurador aumenta con los incrementos en arcilla pero condicionados por su ccc y también regulada por el contenido en carbonatos.\n",
"slide-93":"Bien, en esta gráfica representamos los percentiles de la fracción  As soluble.\nActualmente la comunidad científica no ha llegado ha establecer unos niveles de intervención para el As y metales pesados en la solución del suelo. En su defecto hemos recurrido a los niveles máximos definidos por la FAO para que un agua pueda se utilizada para consumo del ganado. Este nivel de intervención en mg/kg es de 0,08.\nEn el año del vertido un porcentaje importante de los suelos superaba este límite establecido por la FAO. El percentil tiene este valor, o sea el 42% de los suelos se encontraban en situación de toxicidad.\nEn las muestras del 1999 el nivel de intervencion pasa ya al percentil 96. En el 2001 cae al 92 y en el 2004 sólo un suelo superaba el nivel. A partir de esta fecha el 100% de los suelos presenta valores de arsénico soluble por debajo del nivel tóxico.\nEl As soluble muestra una clara tendencia a disminuir con el tiempo. \nEn definitiva, aunque en la zona han quedado importantes concentraciones en As total, este As, afortunadamente, parece encontrarse en estos suelos muy poco activo\n",
"slide-89":"Mucho mas preocupante la zona ácida, con casi la mitad de suelos superando el N.I., mientras que en la zona básica de suelos con carbonatos, los suelos potencialmente contaminados a niveles tóxicos no superan el 20% (exactamente el 18%).",
"slide-5":"En un cuarto punto consideraremos que hubiese pasado en la zona si no se hubiese intervenido",
"slide-19":"En primer lugar, los suelos actuaron como un sistema filtrante que retuvieron las partículas minerales, de tamaño limo, que representaba el tamaño dominante de las partículas de los lodos. La retención fue muy desigual, dependiendo fundamentalmente de las propiedades físicas: textura y estructura de los suelos. ",
"slide-24":"Además de las características de los suelos, la contaminación quedó muy influenciada por la microtopografía de la cuenca. En muy pocos metros la entrada de la contaminación fue muy desigual.",
"slide-94":"La zona hoy día parece no mostrar signos de toxicidad. Este es el aspecto que muestra la ribera del Guadiamar.  Así es como estaba antes del vertido y así estuvo durante las primeras medidas de rehabilitación.",
"slide-7":"Con respecto al primer punto. El accidente.\nComo es conocido, la mina de pirita que la empresa Boliden venía explotando en Aznalcóllar se encuentra situada a unos 30 km al oeste de Sevilla, a unos 40 al norte de las Marismas del Guadalquivir y a unos 50 km del Parque Nacional de Doñana.",
"slide-25":"Para comprobar la contaminación de los suelos, con el ICP-Masas se analizaron los suelos contaminados en los 7 sitios y se compararon con otros tantos suelos fuera del vertido. De los veintitantos elementos químicos analizados ...",
"slide-95":"en la mayor parte de la zona, especialmente en la zona carbonatada, la implantación de la vegetación es muy completa",
"slide-9":"Como es sabido, en la noche del 25/abril/1998, se produce la rotura de una de las paredes de la balsa que retenía los estériles con unas altas concentraciones de As y de metales pesados (del orden de algunos gramos por kg).\nComo resultado de la rotura se produce un vertido de unos 5 hectómetros cúbicos (de los cuales 4 fueron de aguas y 1 de lodos).\n\n",
"slide-30":"pero al quedar sobre la superficie del terreno, los lodos se van desecando, al ir transcurriendo el tiempo, y se va a producir una segunda contaminación aún más peligrosa que la del momento inicial. Efectivamente, al desecarse los lodos, el aire y por tanto el oxigeno va ocupando los poros, y el ambiente se vuelve oxidante",
"slide-96":"aunque, siguen habiendo claros, especialmente en la zona ácida.",
"slide-26":"... fueron 8 los elementos que mostraron fuertes incrementos: antimonio, plomo, arsénico, bismuto, cadmio, cobre, talio y zinc. Podemos decir que la contaminación de los suelos en el vertido de Aznalcóllar se redujo a 8 elementos traza. \nAl Bi no se le consideran hoy día efectos nocivos y el Sb tampoco es tenido en cuenta en la mayoría de las legislaciones europeas sobre suelos contaminados, podemos prescindir de ellos en el seguimiento de esta contaminación. Con lo que nos quedarían 6 contaminantes, 4 predominantes (Pb, As, Cu y Zn) y dos en cantidades muy minoritarias (Cd y Tl). ",
"slide-130":"Por ejemplo, aplicando la ecuac del percentil 95 podemos esperar que a los 38 años la concent del 95% de los s. afectad estará por debajo del N.I. 100 mg/kg.\nY si se mantiene la tendencia actual podría ser que la zona se recupere totalmente a los 117 años del vertido, alcanzando los 18 mg/kg que presentaban los suelos de la cuenca no afectados por el vertido.\nEstos datos deben tomarse con las debidas cautelas, ¡sólo se cumplirán si se mantienen las tendencias actuales!.\nLos valores son muy esperanzadores y sólo espero que Dios nos dé salud a todos para verificalos.\nAVISO. MUCHOS DE LOS DATOS AQUÍ PRESENTADOS CORRESPONDEN A INVESTIGACIONES INÉDITAS DE LOS MIEMBROS DEL DEPARTAMENTO DE EDAFOLOGÍA DE LA UNIVERSIDAD DE GRANADA QUE NO HAN SIDO AÚN PUBLICADOS.",
"slide-31":"Como sabemos, en la pirita tanto el S como el Fe se encuentran en forma reducida y al contacto con el oxígeno del aire ambos se oxidan, primero lo hacen los sulfuros que pasan a sulfatos y luego el Fe2 que pasa a Fe3. \nLa oxidación de sulfuros es un proceso complejo biogeoquímico, en el que participan reacciones de hidratación, oxidación e hidrólisis; y en el que interviene el pH del suelo ya que a pHs muy ácidos las bacterias, como el Thiobacillus ferrooxidans, tienen un papel importantísimo como aceleradores de las reacciones. En definitiva, se liberan importantes cantidades de hidrogeniones y de ácido sulfúrico que van acidificando el medio.\nLa oxidación de sulfuros es un proceso biogeoquímico complejo (Nordstrom, 1982), en el que participan reacciones de hidratación, oxidación e hidrólisis y que se resume de forma muy simplificada en la reacción propuesta por Stumm y Morgan (1981):\nFeS2 + 3.75 O2 + 3.5 H2O\t<==>  Fe(OH)3 + 2 H2SO4\nEsta reacción comprende en realidad una secuencia de reacciones, que pasan, en primer lugar, por la liberación de Fe2+, que en condiciones oxidantes se transforma en Fe3+; si el pH del medio se mantiene por encima de 4.5 (por ejemplo en medios carbonatados) este hierro férrico precipita como hidróxido generando más acidez en el medio:\nFe3+ + 3 H2O\t <==>  Fe(OH)3 + 3 H+\nEl resultado final de la oxidación de la pirita bajo estas condiciones genera una fuerte acidificación del medio (por cada mol de pirita oxidada se producen 4 moles de H+). \nSi por el contrario, el pH del medio se mantiene por debajo de 4.5, o las condiciones son reductoras (Eh < 500 mV), el Fe3+ puede actuar como oxidante de la pirita:\nFeS2 + 14 Fe3+ + 8 H2O  <==>  15 Fe2+ + 2 SO42- + 16 H+\nDe hecho, a pH < 3 el Fe3+ es considerado como el único agente oxidante de estos sulfuros, incluso en condiciones de Eh > 500 mV (Nordstrom, 1982). Esta última reacción de oxidación es mucho más rápida que las anteriores y genera una acidez mucho más elevada (por cada mol de pirita se producen 16 moles de H+). Además, estas reacciones se aceleran enormemente en presencia de bacterias (Thiobacillus ferrooxidans, Leptospirillum ferrooxidans y Thiobacillus thiooxidans), pudiendo llegar a multiplicar por 105 ó 106 las velocidades normales de oxidación .\nEl otro producto generado en las reacciones de oxidación de la pirita son los sulfatos. Debido a las condiciones generalmente ácidas que se producen, la movilidad de los elementos que suelen acompañar a la pirita es elevada, por lo que en última instancia se tenderá a la formación de sulfatos complejos de estos elementos que tenderán a potenciar los efectos de la contaminación debido a su alta solubilidad.",
"slide-97":"Bien, ahora podemos plantearnos, si me permiten la expresión, la pregunta del millón, que hubiese pasado en la cuenca si no se hubiese actuado. En definitiva, ¿Seremos capaces de responder a esta interrogante?.\n\n15´ para la remediación\nHasta aquí 30´",
"slide-27":"En esta comparamos las concentraciones de los suelos contaminados frente a los no contaminados y a los valores medios de los suelos de Andalucía.\nEn primer lugar destaca el fuerte incremento de las concentraciones de los suelos contaminados, a los 10 días del vertido. Por ejemplo, el As pasó de 18 a 122 mg/kg\n\nNOTA: los valores de la CI no coinciden exactamente con los de los suelos contaminados de las anteriores por que se desecho uno de los suelos por no ser representativo (estaba en una vereda que al estar en un primer momento todo recubierto de lodos no nos dimos cuenta).",
"slide-32":"los sulfuros pasan a sulfatos solubles. O sea, las partículas minerales se alteran, se descomponen, liberándose sus iones constituyentes como el As y los metales pesados que pasan a la solución.",
"slide-28":"Con unos fuertes incrementos, que van del 764% para el Pb al 180% para el Zn. \nPero también resulta interesante comparar las concentraciones de los suelos de la cuenca del Guadiamar que no quedaron afectados por el vertido con los valores medios de las concentraciones de los suelos andaluces. Vemos como los suelos de la cuenca del Guadiamar presentan unos valores mucho más altos, lo que pone de manifiesto que antes de este vertido estos suelos ya se encontraban ya moderadamente contaminados como resultado de la prologada explotación de esta mina, desde el tiempo de los romanos.\nNota los incrementos parecen no cuadrar exactamente pero esto es debido a que los números originales tenían dos decimales",
"slide-98":"Pues gracias a que la Junta de Andalucía dejó dos parcelas para investigación con la recubierta de lodos sin retirar, en la zona del Vado del Quema",
"slide-127":"114 cm a los 100 años, o sea a los 100 años se hubiese producido la anulación de todo el espesor del suelo.\nPero no pretendo dramatizar, pues recordemos, esto hubiese ocurrido si no se hubiese procedido a la mediación de la zona.",
"slide-33":"Este proceso se comprobó ya en las muestras del segundo muestreo. A sólo 16 días del primer muestreo en los extractos solubles de los lodos se produce un fuerte incremento de los sulfatos (del orden de 10 a 30 veces), con una fuerte bajada del pH (de más de dos unidades) y se produce",
"slide-99":"Y también nosotros al rastrear a fondo la zona hemos encontrado varios puntos aislados repartidos por la cuenca que escaparon a la retirada de los lodos. Podemos intentar responder a esta cuestión.",
"slide-29":"Bien en esta situación inicial los lodos al caer sobre los suelos ... ... ... pirita ...",
"slide-34":"un espectacular incremento en las concentraciones de metales en la solución de los lodos (pasando desde pocas decenas a miles de mg/kg), y todo esto ocurría, no lo olvidemos, en una capa que estaba encima de los suelos.",
"slide-128":"En la zona remediada, fuera de las parcelas experimentales, el futuro parece muy diferente. Como hemos visto al hablar de las medidas de rehabilitación, las concentraciones del As total y metales pesados han ido sistemáticamente decreciendo al ir transcurriendo el tiempo, como muestra esta tabla para las concentraciones en As de distintos percentiles.\nSi representamos estas tendencias en una curva de regresión",
"slide-132":"Por último quiero agradecer a Antonio Lafuente haberse acordado de mí para esta charla y haberme dado la oportunidad de contaros como reaccionaron mis compañeros del Dpto  UGR frente a esta situación inédita para ellos que se les presentó, y haberme sacado de mi monótona vida de jubilado ....\nBueno  no, esto en realidad es una versión que  contamos los jubilados a los amigos que siguen trabajando pero en realidad la situación es bastante distinta...\n",
"slide-35":"Que en los lodos estaban ocurriendo cosas lo comprobamos en seguida, en nuestra segunda visita. La superficie se había vuelto completamente blanca, como si se hubiese producido una nevada.",
"slide-129":"Se obtienen unas ecuaciones de regresión con unos ajustes realmente altos para los percentiles 50, 90, 95 y 99, con un R2 de 0,97 y 0,98.\nEstas ecuaciones nos van a permitir adentrarnos en el futuro de la zona.",
"slide-40":"Efectivamente, aquí mostramos como ya en el segundo muestreo, con unas lluvias en la zona de 45 L/m2, los suelos (insisto estamos hablando ya de lo que ocurre en los suelos, no en los lodos como era el caso de las pantallas anteriores) pues bien, los suelos muestran fuertes incrementos, (los datos del primer muestreo en blanco y el segundo muestreo en rojo) aquí mostramos el caso del Zn y del Cu pero similar comportamiento lo presenta el resto de los contaminantes.\nAsí, de esta manera los suelos resultan fuertemente contaminados, cada vez más, conforme iba transcurriendo el tiempo y de aquí surge la necesidad imperiosa de retirar la capa de lodos que recubre a los suelos.",
"slide-36":"Los sulfuros de la superficie de los lodos se oxidaban y se formaban sales.\nBianchita\nBeaverita\nHexaedrita",
"slide-133":"¡Ay, los nietos! ¡qué sería de los jubilados sin sus nietos ... y ¡sin Carrefour!",
"slide-41":"De manera que valores medios de los suelos en su horizonte superficial a sólo tres meses del vertido, al final de julio, transcurridos sólo tres meses del vertido, eran muy altos, por ejemplo la concentración de As pasó de 122 a 213 mg/kg. A esta contaminación secundaria, por su causa, la llamamos contaminación oxidativa, ",
"slide-37":"Por otra parte, en el interior de los lodos al seguir desecándose, los sulfatos y los metales pasaban a la solución pero quedaban retenidos en los lodos, concretamente en la solución que formaba delgadas películas de agua higroscópica y capilar.\n",
"slide-38":"Todo esto ocurría en el periodo seco, pero con la llegada de las primeras lluvias ...\nPrimero las sales depositadas en la superficie se disolvían y penetraban dentro de los lodos,",
"slide-42":"Bien esta contaminación secundaria suponía unos incrementos del orden de un 70%, con unos máximos del 159% para el Cd, con respecto a las concentraciones de la contaminación inicial",
"slide-43":"y que alcanzan valores extremos si se comparan con las concentraciones presentes en los suelos antes del vertido, con incrementos totales de hasta el 1.083%, caso del As, a sólo tres meses del vertido pasa de 18 a 213 mg/kg.",
"slide-100":"Tanto en los suelos básicos como en los ácidos los perfiles muestran una intensa modificación. Así al cabo de los 3 años aparece muy nítida una capa de color blanco en la parte superior del suelo en el contacto con la capa de lodos y debajo de esta aparece otra capa de color rojizo. Estas capas son el resultado de intensas alteraciones y contaminaciones.\n",
"slide-39":"Y en el interior la capa de lodos se satura de agua de lluvia, este agua inunda los macroporos que carecen de capacidad de retención del agua, es en definitiva agua de gravedad que ya no puede ser retenida y se infiltran en el suelo produciendo una nueva contaminación, la contaminación secundaria, que podemos denominar como contaminación oxidativa.\n",
"slide-44":"Ante esta situación había que intervenir para rehabilitar la zona, lo primero que había que hacer estaba claro: ¡la retirada de la capa de lodos que recubría los suelos! y además había que hacerlo lo más rápidamente posible ya que a la luz de los resultados aquella capa de lodos representaba una auténtica bomba química de relojería. Y así se le comunicó a la Junta de Andalucía y la Junta, así lo hizo.\n\nhasta aquí 15´ ",
"slide-101":"En todos estos puntos con lodos hemos realizado un muestreo sistemático de los perfiles, tomando muestras cada 1, 5, 10 y 20 cm, según la profundidad. Realizando, en algunos casos, un seguimiento desde los 2 meses hasta los 9 años.\n",
"slide-45":"Así nos encontramos la zona a los 10 días del vertido"}
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"creator":"Apple Keynote 5.1.1",
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